{"id":2653,"date":"2017-11-22T12:05:54","date_gmt":"2017-11-22T15:05:54","guid":{"rendered":"http:\/\/cursos.ufrrj.br\/posgraduacao\/ppgq\/?page_id=2653"},"modified":"2017-11-22T12:05:54","modified_gmt":"2017-11-22T15:05:54","slug":"ic-1365","status":"publish","type":"page","link":"https:\/\/cursos.ufrrj.br\/posgraduacao\/ppgq\/atividades-disciplinares\/ic-1365\/","title":{"rendered":"IC-1365 – Qu\u00edmica Inorg\u00e2nica Avan\u00e7ada II"},"content":{"rendered":"

4 cr\u00e9ditos 60 horas te\u00f3ricas<\/strong><\/p>\n

 <\/p>\n

OBJETIVOS<\/strong>:<\/p>\n

Apresentar conhecimentos sobre m\u00e9todos f\u00edsicos de caracteriza\u00e7\u00e3o de compostos inorg\u00e2nicos: fundamentos de espectroscopia eletr\u00f4nica de compostos de coordena\u00e7\u00e3o, das espectroscopias vibracionais no infravermelho e Raman, e de resson\u00e2ncia magn\u00e9tica multinuclear (RMN) aplicadas aos compostos inorg\u00e2nicos.<\/p>\n

 <\/p>\n

EMENTA<\/strong>:<\/p>\n

1.\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Espectroscopia eletr\u00f4nica de compostos de coordena\u00e7\u00e3o<\/p>\n

2.\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Espectroscopia vibracional no infravermelho e Raman<\/p>\n

3.\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Resson\u00e2ncia magn\u00e9tica multinuclear (RMN multinuclear)<\/p>\n

 <\/p>\n

CONTE\u00daDO PROGRAM\u00c1TICO:<\/strong><\/p>\n

1. Espectroscopia eletr\u00f4nica<\/p>\n

1.1. Fundamentos da t\u00e9cnica.<\/p>\n

1.2. Termos espectrais para as configura\u00e7\u00f5es eletr\u00f4nicas d e seus desdobramentos em campos octa\u00e9drico, tetra\u00e9drico e quadrado.<\/p>\n

1.3. Diagramas de correla\u00e7\u00e3o: Orgel e Tanabe-Sugano.<\/p>\n

1.4. C\u00e1lculos de Do e B.<\/p>\n

1.5. Regras de sele\u00e7\u00e3o.<\/p>\n

1.6. Cores e efeitos batocr\u00f4mico e hipsocr\u00f4mico.<\/p>\n

1.7. Efeito do solvente e tipo de transi\u00e7\u00e3o.<\/p>\n

2. Espectroscopia vibracional no infravermelho e Raman<\/p>\n

2.1. Fundamentos das t\u00e9cnicas.<\/p>\n

2.2. Regras de sele\u00e7\u00e3o para espectros infravermelho e Raman.<\/p>\n

2.3. Aplica\u00e7\u00f5es em qu\u00edmica inorg\u00e2nica: mol\u00e9culas diat\u00f4micas e poliat\u00f4micas.<\/p>\n

2.4. Aplica\u00e7\u00f5es em qu\u00edmica inorg\u00e2nica: compostos de coordena\u00e7\u00e3o e organomet\u00e1licos.<\/p>\n

3. Resson\u00e2ncia magn\u00e9tica multinuclear (RMN)<\/p>\n

3.1. RMN de 195Pt: Fundamentos e aplica\u00e7\u00f5es<\/p>\n

3.2. RMN de 31P: Fundamentos e aplica\u00e7\u00f5es<\/p>\n

3.3. RMN de 15N: Fundamentos e aplica\u00e7\u00f5es<\/p>\n

 <\/p>\n

METODOLOGIA<\/strong>:<\/p>\n

Aulas expositivas, com recursos did\u00e1ticos diversos (quadro\/giz, data show, multim\u00eddia e computadores). Os alunos ser\u00e3o avaliados com semin\u00e1rios individuais e trabalhos individuais ou em grupos.<\/p>\n

 <\/p>\n

BIBLIOGRAFIA B\u00c1SICA<\/strong><\/p>\n

a) Miessler, G. L., Tarr, D. A. \u201cInorganic Chemistry\u201d; 4th Ed. New Jersey, Pearson, 2011.<\/p>\n

b) Cotton, F. A., Wilkinson, G., Murillo, C.A., Bochmann, M., \u201cAdvanced Inorganic Chemistry\u201d; 6th Ed. New York, John Wiley & Sons, 1999.<\/p>\n

c) Deeth, R. J., Ligand Field Theory. In: Comprehensive Coordination Chemistry II. 2nd ed. Exeter, Vol. 2, Elsevier, 2005.<\/p>\n

d) Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th ed. Wiley Interscience, 1997.<\/p>\n

e) Ebsworth, E. A. V., \u00a0Rankin, D.W.H.,\u00a0 Cradock, S., Structural Methods in Inorganic Chemistry. Blackwell, 1987.<\/p>\n

f) Artigos de peri\u00f3dicos especializados de circula\u00e7\u00e3o internacional.<\/p>\n","protected":false},"excerpt":{"rendered":"

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